Journal of the European Optical Society - Rapid publications, Vol 4 (2009)

Tuning optical properties of opal photonic crystals by structural defects engineering

F. Di Stasio, M. Cucini, L. Berti, Davide Comoretto, A. Abbotto, L. Bellotto, N. Manfredi, C. Marinzi


We report on the preparation and optical characterization of three dimensional colloidal photonic crystal (PhC) containing an engineered planar defect embedding photoactive push-pull dyes. Free standing polystyrene films having thickness between 0.6 and 3 microns doped with different dipolar chromophores were prepared. These films were sandwiched between two artificial opals creating a PhC structure with planar defect. The system was characterized by reflectance at normal incidence angle (R), variable angle transmittance (T), and photoluminescence spectroscopy (PL). Clear evidence of defect states were observed in T and R spectra, which allow the light to propagate for selected frequencies within the pseudogap (stop band).

© The Authors. All rights reserved. [DOI: 10.2971/jeos.2009.09033]

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E. Yablonovitch, "Inhibited spontaneous emission in solid-state physics and electronics" Phys. Rev. Lett. 58, 2059 (1987).

S. John, "Strong localization of photons in certain disordered dielectric superlattices" Phys. Rev. Lett. 58, 2486 (1987).

D. J. Norris, E. G. Arlinghaus, L. Meng, R. Heiny, and L. E. Scriven, "Opaline photonic crystals: how does self-assembly work?" Adv. Mater. 16, 1393 (2004).

Y. Xia, B. Gates, and Z. Y. Li, "Self-assembly approaches to threedimensional photonic crystals" Adv. Mater. 13, 409 (2001).

J. E. G. J. Wijnhoven and W. L. Vos, "Preparation of photonic crystals made of air spheres in titania" Science 281, 802 (1998).

A. A. Zakhidov, R. H. Baughman, Z. Iqbal, C. Cui, I. Khayrullin, S. O. Dantas, J. Marti, and V. G. Ralchenko, "Carbon structures three-dimensional periodicity at optical wavelengths" Science 282, 897 (1998).

D. J. Norris and Y. A. Vlasov, "Chemical approaches to threedimensional semiconductor photonic crystals" Adv. Mater. 13, 371 (2001).

S. G. Romanov, T. Maka, C. M. S. Torres, M. Muller, and R. Zentel, "Light emission from thin opaline photonic crystals of low and high dielectric contrast" Synthetic Met. 124, 131 (2001).

A. Blanco, E. Chomski, S. Grabtchak, M. Ibisate, S. John, S. W. Leonard, C. Lopez, F. Meseguer, H. Miguez, J. P. Mondia, G. A. Ozin, O. Toader, and H. M. v. Driel, "Large-scale synthesis of a silicon photonic crystal with a complete three-dimensional bandgap near 1.5 micrometres" Nature 405, 437 (2000).

P. Jiang, J. F. Bertone, K. S. Hwang, and V. L. Colvin, "Single-crystal colloidal multilayers of controlled thickness" Chem. Mater. 11, 2132 (1999).

P. Jiang, J. F. Bertone, and V. L. Colvin, "A lost-wax approach to monodisperse colloids and their crystals" Science 291, 453 (2001).

F. Jonsson, C. M. S. Torres, J. Seekamp, M. Schniedergers, A. Tiedemann, J. Ye, and R. Zentel, "Artificially inscribed defects in opal photonic crystals" Microelectron. Eng. 78-79, 429 (2005).

T. A. Taton and D. J. Norris, "Device physics: Defective promise in photonics" Nature 416, 685 (2002).

Y. A. Vlasov, X. Z. Bo, J. C. Sturm, and D. J. Norris, "On-chip natural assembly of silicon photonic bandgap crystals" Nature 414, 289 (2001).

V. N. Astratov, A. M. Adawi, S. Fricker, M. S. Skolnick, D. M. Whittaker, and P. N. Pusey, "Interplay of order and disorder in the optical properties of opal photonic crystals" Phys. Rev. B 66, 165215 (2002).

Y. A. Vlasov, V. N. Astratov, A. V. Baryshev, A. A. Kaplyanskii, O. Z. Karimov, and M. F. Limonov, "Manifestation of intrinsic defects in optical properties of self-organized opal photonic crystals" Phys. Rev. E 61, 5784 (2000).

Y. A. Vlasov, M. Deutsch, and D. J. Norris, "Single-domain spectroscopy of self-assembled photonic crystals" Appl. Phys. Lett. 76, 1627 (2000).

J. F. Galisteo Lòpez and W. L. Vos, "Angle-resolved reflectivity of single-domain photonic crystals: Effects of disorder" Phys. Rev. E 66, 036616 (2002).

C. A. Fustin, G. Glasser, H. W. Spiess, and U. Jonas, "Site-selective growth of colloidal crystals with photonic properties on chemically patterned surface" Adv. Mater. 15, 1025 (2003).

X. Y. Ling, I. Y. Phang, W. Maijenburg, H. Schönherr, D. N. Reinhoudt, G. J. Vancso, and J. Huskens, "Free-standing 3D supramolecular hybrid particle structures" Angew. Chem. Int. Edit. 48, 983 (2009).

J. D. Joannopulos, R. D. Meade, and J. N. Win, Photonic Crystals: Molding the Flow of the Light (Princeton University Press, Princeton, 1995).

C. Lopez, "Materials aspects of photonic crystals" Adv. Mater. 15, 1679 (2003).

D. Comoretto, V. Morandi, F. Marabelli, V. Amendola, and M. Meneghetti, "Optical effects in artificial opals infiltrated with gold nanoparticles" SPIE Proc. Ser. 6182, 61820D (2006).

V. Morandi, F. Marabelli, V. Amendola, M. Meneghetti, and D. Comoretto, "Colloidal photonic crystals doped with gold nanoparticles; spectroscopy & optical switching properties" Adv. Funct. Mater. 17, 2770 (2007).

V. Morandi, F. Marabelli, V. Amendola, M. Meneghetti, and D. Comoretto, "Light localization effect on the optical properties of opals doped with gold nanoparticles" J. Phys. Chem. C 112, 6293 (2008).

M. Cucini, D. Comoretto, M. Galli, F. Marabelli, A. Abbotto, L. Bellotto, and C. Marinzi, "Emission properties of artificial opals infiltrated with a heteroaromatic quadrupolar dye" SPIE Proc. Ser. 6999, 69992D (2008).

D. Comoretto, F. Marabelli, C. Soci, M. Galli, E. Pavarini, M. Patrini, and L. C. Andreani, "Morphology and optical properties of bare and polydiacetylenes-infiltrated opals" Synthetic Met. 139, 633 (2003).

E. P. Petrov, V. N. Bogomolov, I. I. Kalosha, and S. V. Gaponenko, "Spontaneous Emission of Organic Molecules Embedded in a Photonic Crystal" Phys. Rev. Lett. 81, 77 (1998).

M. Deutsch, Y. A. Vlasov, and D. J. Norris, "Conjugated-polymer photonic crystals" Adv. Mater. 12, 1176 (2000).

N. Eradat, A. Y. Sivachenko, M. E. Raikh, Z. V. Vardeny, A. A. Zakhidov, and R. H. Baughman, "Evidence for braggoriton excitations in opal photonic crystals infiltrated with highly polarizable dyes" Appl. Phys. Lett. 80, 3491 (2002).

N. Eradat, M. Wohlgenannt, Z. V. Vardeny, A. A. Zakhidov, and R. H. Baughman, "Studies of optical transitions related to piconjugated polymers and laser dyes infiltrated in opal photonic crystals" Synthetic Met. 116, 509 (2001).

J.-C. Hong, J. H. Park, C. Chun, and D. Y. Kim, "Photoinduced tuning of optical stop bands in azopolymer based inverse opal photonic crystals" Adv. Funct. Mater. 17, 2462 (2007).

M. N. Shkunov, Z. V. Vardeny, M. C. DeLong, R. C. Polson, A. A. Zakhidov, and R. H. Baughman, "Tunable, gap-state lasing in switchable directions for opal photonic crystals" Adv. Funct. Mater. 12, 21 (2002).

R. C. Polson, A. Chipouline, and Z. V. Vardeny, "Random Lasing in p-Conjugated Films and Infiltrated Opals" Adv. Mater. 13, 760 (2001).

R. C. Polson and Z. V. Vardeny, "Organic random laser in the weakscattering regime" Phys. Rev. B 71, 045205 (2005).

P. Markowicz, C. Friend, Y. Shen, J. Swiatkiewicz, P. N. Prasad, O. Toader, S. John, and R. W. Boyd, "Enhancement of two-photon emission in photonic crystals" Opt. Lett. 27, 351 (2002).

J. D. Joannopoulos, P. R. Villeneuve, and S. Fan, "Photonic crystals: putting a new twist on light" Nature 386, 143 (1997).

P. V. Braun, S. A. Rinne, and F. Garcia-Santamaria, "Introducing defects in 3D photonic crystals: state of the art" Adv. Mater. 18, 2665 (2006).

Y. H. Ye, T. S. Mayer, I. C. Khoo, I. B. Divliansky, N. Abrams, and T. E. Mallouk, "Self-assembly of three-dimensional photoniccrystals with air-core line defects" J. Mater. Chem 12, 3637 (2002).

Q. Yan, Z. Zhou, X. S. Zhao, and S.J. Chua, "Line defects embedded in three-dimensional photonic crystals" Adv. Mater. 17, 1917 (2005).

J. F. Galisteo-Lopez, M. Galli, L. C. Andreani, A. Mihi, R. Pozas, M. Ocana, and H. Miguez, "Phase delay and group velocity determination at a planar defect state in three dimensional photonic crystals" Appl. Phys. Lett. 90, 101113 (2007).

D. L. C. Chan, E. Lidorikis, and J. D. Joannopoulos, "Point defect geometries in inverted opal photonic crystals" Phys. Rev. E 71, (2005).

E. Palacios-Lidon, J. F. Galisteo-Lopez, B. H. Juarez, and C. Lopez, "Engineered planar defects embedded in opals" Adv. Mater. 16, 341 (2004).

Q. Yan, Z. Zhou, and X. S. Zhao, "Introduction of three-dimensional extrinsic defects into colloidal photonic crystals" Chem. Mater. 17, 3069 (2005).

S. Furumi, H. Fudouzi, H. T. Miyazaki, and Y. Sakka, "Flexible polymer colloidal-crystal lasers with a light-emitting planar defect" Adv. Mater. 19, 2067 (2007).

N. Tetreault, A. Mihi, H. Miguez, I. Rodriguez, G. A. Ozin, F. Meseguer, and V. Kitaev, "Dielectric planar defects in colloidal photonic crystal films" Adv. Mater. 16, 346 (2004).

J. R. Lawrence, Y. Ying, P. Jiang, and S. H. Foulger, "Dynamic tuning of organic lasers with colloidal crystals" Adv. Mater. 18, 300 (2006).

L. Wang, Q. Yan, and X. S. Zhao, "From planar defect in opal to planar perfect in inverse opal" Langmuir 22, 3481 (2006).

S. Noda, A. Chutian, and M. Imada, "Trapping and emission of photons by a single defect in a photonic bandgap structure" Nature 407, 608 (2000).

O. Painter, R. K. Lee, A. Scherer, A. Yariv, J. D. O'Brien, P. D. Dapkus, and I. Kim, "Two-dimensional photonic band-gap defect mode laser" Science 284, 1819 (1999).

R. Pozas, A. Mihi, M. Ocana, and H. Miguez, "Building nanocrystalline planar defects within self-assembled photonic crystals by spin-coating" Adv. Mater. 18, 1183 (2006).

A. Arsenault, F. Fleischhaker, G. v. Freymann, V. Kitaev, H. Miguez, A. Mihi, N. Tetreault, E. Vekris, I. Manners, S. Aitchison, D. Perovic, and G. A. Ozin, "Perfecting imperfection-designer defects in colloidal photonic crystals" Adv. Mater. 18, 2779 (2006).

Q. Yan, L. K. Teh, Q. Shao, C. C. Wong, and Y. M. Chiang, "Layer transfer approach to opaline hetero photonic crystals" Langmuir 24, 1796 (2008).

N. Tetreault, A. C. Arsenault, A. Mihi, S. Wong, V. Kitaev, I. Manners, H. Miguez, and G. A. Ozin, "Building tunable planar defects into phoyonics crystals using polyelectrolyte multilayers" Adv. Mater. 17, 1912 (2005).

F. Fleischhaker, A. C. Arsenault, J. Schmidtke, R. Zentel, and G. A. Ozin, "Spin-coating of designed functional planar defects in opal film: generalized synthesis" Chem. Mater. 18, 5640 (2006).

N. Tetreault, H. Miguez, S. M. Yang, V. Kitaev, and G. A. Ozin, "Refractive index patterns in silicon inverted colloidal photonic crystals" Adv. Mater. 15, 1167 (2003).

Y. Jun, C. A. Leatherdale, and D. J. Norris, "Tailoring air defects in self-assembled photonic bandgap crystals" Adv. Mater. 17, 1908 (2005).

F. Fleischhaker, A. C. Arsenault, V. Kitaev, F. C. Peiris, G. v. Freymann, I. Manners, R. Zentel, and G. A. Ozin, "Photochemically and thermally tunable planar defects in colloidal photonic crystals" J. Am. Chem. Soc. 127, 9318 (2005).

Q. Yan, A. Chen, S. J. Chua, and X. S. Zhao, "Incorporation of point defects into self-assembled three-dimensional colloidal crystals" Adv. Mater. 17, 2849 (2005).

P. Massé, S. Reculusa, K. Clays, and S. Ravaine, "Tailoring planar defect in three-dimensional colloidal crystals" Chem. Phys. Lett. 422, 251 (2006).

Q. Yan, L. Wang, and X. S. Zhao, "Artificial defect engineering in three-dimensional colloidal photonic crystals" Adv. Funct. Mater. 17, 3695 (2007).

W. Lee, S. A. Pruzinsky, and P. V. Braun, "Multi-photon polymerization of waveguide structures within three-dimensional photonic crystals" Adv. Mater. 14, 271 (2002).

J. Feng, S. Yang, D. Xian-Zi, C. Wei-Qiang, and D. Xuan-Ming, "Amplified spontaneous emission from dye-doped polymer film sandwiched by two opal photonic crystals" Appl. Phys. Lett. 91, 031109 (2007).

F. Jin, C.-F. Li, X.-Z. Dong, W.-Q. Chen, and X.-M. Duan, "Laser emission fron dye-doped polymer film in opal photonic crystal cavity" Appl. Phys. Lett. 89, 241101 (2006).

A. Abbotto, L. Beverina, S. Bradamante, A. Facchetti, C. Klein, G. A. Pagani, M. Redi-Abshiro, and R. Wortmann, "A distintive example of the cooperative interplay of structure and environment in tuning of intramolecular charge transfer in second-order nonlinear optical chromophores" Chem. Eur. J. 9, 1991 (2003).

G. Archetti, A. Abbotto, and R. Wortmann, "Effect of polarity and structural design on molecular photorefractive properties of heteroaromatic-based push-pull dyes" Chem. Eur. J. 12, 7151 (2006).

M. Pope and C. E. Swenberg, Electronic processes in organic crystals and polymers (Oxford University Press, New York, 1999).